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Large volumes have been written on paste jewels, especially on antique pastes. Contrary to a prevailing belief, the paste gem is not a recent invention. People frequently say when told that their gems are false, "But it is a very old piece, it must be genuine." The great age of a jewel should rather lead to suspicion that it was not genuine than give confidence that a true gem was assured. The Egyptians and Romans were skillful makers of glass of the sort used in imitating gems and some of the old pastes were very hard or else have become so with age.
Glass of one variety or another makes the most convincing sort of imitation precious stones. The term "paste" as applied to glass imitations is said to come from the Italian pasta meaning dough, and it suggests the softness of the material. Most pastes are mainly lead glass. As we saw in the lesson on the chemical composition of the gems, many of them are silicates of metals. Now glasses are also silicates of various metals, but unlike gem minerals the glasses are not crystalline but rather amorphous, that is, without definite geometric form or definite internal arrangement.
The optical properties of the various glasses vary chiefly with their densities, and the denser the material the higher the refractive index and the greater the dispersion. Thus to get the best results in imitation stones they should be made of very heavy glass. The dense flint glass (chiefly a silicate of potassium and lead) which is used for cut glass ware illustrates admirably the optical properties of the heavy glasses. By using even more lead a still denser glass may be had, with even a greater brilliancy.
Unfortunately the addition of lead or other heavy metals (such as thallium) makes the product very soft and also very subject to attack by gases such as are always present in the atmosphere of cities. This softness causes the stones to scratch readily so that when worn they soon lose their polish and with the loss of polish they lose their beauty. The attack of the gases before mentioned darkens the surfaces of the imitation and further dulls it. When fresh and new a well cut piece of colorless paste has a snap and fire that approaches that of diamond. The surface luster is not adamantine, however, and the edges of the facets cannot be polished so sharply as those on a diamond. Moreover the refractive index, while high, is never so high as in a diamond and hence the brilliant cannot be so shaped as to secure the amount of total reflection given by a well-made diamond. Hence, the paste brilliant, while quite satisfying as seen from squarely in front, is weak and dark in the center as seen when tilted to one side. By these differences the trained eye can detect paste imitations of diamond at a glance without recourse to tests of specific gravity, hardness, etc.
Pastes, being amorphous, are singly refracting, as is diamond. This fact helps the appearance of the paste brilliant, for light does not divide within it to become weakened in power. This singleness of refraction, however, betrays the paste imitation when it is colored to resemble ruby, sapphire or emerald, all of which are doubly refracting.
The color is imparted to pastes by the addition, during their manufacture, of various metallic oxides in small proportions. Thus cobalt gives a blue color, copper or chromium green, copper or gold give red (under proper treatment) and manganese gives purple. By experiment the makers of pastes have become very skillful in imitating the color of almost any precious stone. Fine paste emeralds may look better than inferior genuine emeralds.
As pastes are singly refracting and hence lack dichroism, the pleasing variety of color of the true ruby cannot be had in a paste imitation, but the public is not critical enough to notice this lack. The expert would, however, note it and could detect the imitation by that difference as well as by the lack of double refraction. The use of direct sunlight and a white card as already explained in the lesson on double refraction will serve to expose the singleness of refraction of paste imitations. Spinels and garnets are about the only true gems (except diamond) that are single refracting. Any other color stone should show double refraction when tested by the sunlight-card method. The file test will also expose any paste imitation as all the very brilliant pastes are fairly soft. |
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Precious Stones Guide Vol 7
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